ChemInform Abstract: A General Strategy for the Perfluoroalkylation of Arenes and Arylbromides by Using Arylboronate Esters and [(phen)CuRF].

Nichole D. Litvinas; Patrick S. Fier; John F Hartwig

doi:10.1002/chin.201222059

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ChemInform Abstract: A General Strategy for the Perfluoroalkylation of Arenes and Arylbromides by Using Arylboronate Esters and [(phen)CuRF].

Article 2012 en

Abstract

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Abstract A wide range of aryl perfluoroalkanes is synthesized from arenes (I) and aryl bromides (IV) via in situ generated aryl boronate esters which undergo subsequent perfluoroalkylation in air with (phen)CuR (II).

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ChemInform Abstract: A General Strategy for the Perfluoroalkylation of Arenes and Arylbromides by Using Arylboronate Esters and [(phen)CuR<sup>F</sup>].

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Related publications

A General Strategy for the Perfluoroalkylation of Arenes and Arylbromides by Using Arylboronate Esters and [(phen)CuR<sup>F</sup>]

A General Strategy for the Perfluoroalkylation of Arenes and Arylbromides by Using Arylboronate Esters and [(phen)CuR<sup>F</sup>]

ChemInform Abstract: A C—H Borylation Approach to Suzuki—Miyaura Coupling of Typically Unstable 2—Heteroaryl and Polyfluorophenyl Boronates.

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A Combined Spectroscopic and Computational Study on the Mechanism of Iron-Catalyzed Aminofunctionalization of Olefins Using Hydroxylamine Derived N–O Reagent as the “Amino” Source and “Oxidant”