Changing the Behavior of Chromophores from Aggregation‐Caused Quenching to Aggregation‐Induced Emission: Development of Highly Efficient Light Emitters in the Solid State

Efficient solid-state emitters developed by a new approach are described. While emission from triphenylamine (TPA) and its dimer (DTPA) is weakened by aggregation, attaching tetraphenylethene (TPE) units to the amines boosts their emission efficiencies up to 100% in the aggregate state without harming their hole-transport properties. The resultant 3TPETPA and 4TPEDTPA luminogens show excellent electroluminescence performance. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.