Carbon nanotubes as non-contact optical strain sensors in smart skins

Progress is reported in the development of a novel non-contact strain measurement technology in which the sensors are single-walled carbon nanotubes. This approach exploits the characteristic short-wave infrared fluorescence signatures of semiconducting single-walled carbon nanotubes and the systematic shifts of their fluorescence wavelengths when the nanotubes are axially strained. A strain-sensing smart skin is prepared by coating the surface to be monitored with a thin film of a composite containing well-dispersed single-walled carbon nanotubes embedded in a urethane varnish host. Strain in the surface transfers through the host polymer to the embedded nanotubes. The nanotube strains are then quantitatively monitored by exciting the region of interest with a visible laser beam and capturing and analyzing the resulting single-walled carbon nanotube fluorescence spectrum. High-quality spectra are shown for strain-sensing smart skin films in which the nanotubes were pre-processed by selective extraction with the organic polymer poly(9,9-dioctylfluorenyl-2,7-diyl) and purification by centrifugation. The design of a compact, field-portable optical system for exciting, collecting, and interpreting strain-sensing smart skin spectral data is also described. This system is used to validate the linear dependence of peak shifts with strain in test specimens subjected to multiple tension cycles inducing strains from 0 to 5000 µε. Adequate linearity is found up to 1500 µε; however, minor hysteresis is observed above this level. The gage length for these measurements can be as small as several micrometers, and the strain resolution is currently between 10 and 100 µε (depending on strain magnitude). Cyclic reversible strain measurements are demonstrated, with minor hysteresis being attributed to imperfect adhesion between nanotube sidewalls and the surrounding polymer host.