Backbone editing and deconstruction of polyethylene by Beckmann rearrangement and hydrogenolysis

Jake X. Shi; Diane D. Kim; Nicodemo R. Ciccia; Pierre Lahaie-Boivin; John F Hartwig

doi:10.1039/d5sc02684a

Abstract

1 min read

Conversion of oxime-modified polyethylenes to polyamides by Beckmann rearrangement creates materials with enhanced adhesion. Deconstruction by hydrogenolysis furnishes fragments that serve as precursors for new materials.

Related publications

Article2010

In situ multinuclear solid-state NMR spectroscopy study of Beckmann rearrangement of cyclododecanone oxime in ionic liquids: The nature of catalytic sites

Teresa Blasco, Avelino Avelino, Sara Iborra, Inés Lezcano‐González, Raquel Montón

Journal of Catalysis

Article2007

Nanosized and delayered zeolitic materials for the liquid-phase Beckmann rearrangement of cyclododecanone oxime

Pablo Botella, Avelino Avelino, Sara Iborra, Raquel Montón, Isabelle Rodríguez, V. Da Costa

Journal of Catalysis

Article2007

NMR spectroscopy and theoretical calculations demonstrate the nature and location of active sites for the Beckmann rearrangement reaction in microporous materials

Ana M. Cameán, Inés Lezcano‐González, Mercè Boronat, Teresa Blasco, Avelino Avelino

Journal of Catalysis

Article1991

Beckmann rearrangement of cyclohexanone oxime on zeolites

Avelino Avelino, Hermenegildo Garcı́a, Jaime Primo, Enrique Sastre

Zeolites

Article1998

Active sites for the liquid-phase beckmann rearrangement of cyclohexanone, acetophenone and cyclododecanone oximes, catalyzed by beta zeolites

Miguel Á. Camblor, Avelino Avelino, Hermenegildo Garcı́a, V. Semmer-Herledan, Susana Valencia

Journal of Catalysis

Backbone editing and deconstruction of polyethylene by Beckmann rearrangement and hydrogenolysis

Abstract

Discussion(0)

Related publications

In situ multinuclear solid-state NMR spectroscopy study of Beckmann rearrangement of cyclododecanone oxime in ionic liquids: The nature of catalytic sites

Nanosized and delayered zeolitic materials for the liquid-phase Beckmann rearrangement of cyclododecanone oxime

NMR spectroscopy and theoretical calculations demonstrate the nature and location of active sites for the Beckmann rearrangement reaction in microporous materials

Beckmann rearrangement of cyclohexanone oxime on zeolites

Active sites for the liquid-phase beckmann rearrangement of cyclohexanone, acetophenone and cyclododecanone oximes, catalyzed by beta zeolites