Azulene based metal–organic frameworks for strong adsorption of H2
Article 2010 en
Authors
SB
Samir Barman
HF
Hiroyasu Furukawa
OB
Olivier Blacque
Abstract
1 min read
Two Zn MOFs, MOF-645 and MOF-646, comprised of polarized 1,3-azulenedicarboxylate were synthesized. The guest free MOF-646 showed strong MOF-H(2) interactions (7.8-6.8 kJ mol(-1)), which revealed the significant impact of internally polarized azulene backbone to stabilized H(2) molecules in the framework.
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