An Unusual Open-Framework Cobalt(II) Phosphate with a Channel Structure That Exhibits Structural and Magnetic Transitions — Amitava Choudhury (2000) | RDL Network
An Unusual Open-Framework Cobalt(II) Phosphate with a Channel Structure That Exhibits Structural and Magnetic Transitions
Angewandte Chemie International Edition 39(17): 3091-3093
Article 2000 English
Authors
AC
Amitava Choudhury
SN
S. Neeraj
SN
Srinivasan Natarajan
Abstract
1 min read
Magnetic and structural transitions at low temperatures are exhibited by the novel open-framework cobalt(II) phosphate of the composition [enH2][Co3.5(PO4)3] (en=ethylenediamine), the structure of which contains 12-membered channels (see picture). In the presence of a magnetic field, the compound undergoes a transition between two ferrimagnetic states.
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