Advanced supramolecular initiator for nitroxide-mediated polymerizations containing both metal-ion coordination and hydrogen-bonding sites

Ulrich Mansfeld; Martin D. Hager; Richard Hoogenboom; Christina Ott; Andreas Winter; Ulrich Sigmar Schubert

doi:10.1039/b902636c

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Advanced supramolecular initiator for nitroxide-mediated polymerizations containing both metal-ion coordination and hydrogen-bonding sites

Article 2009 en

Abstract

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The synthesis of a new difunctional nitroxide initiator combining two orthogonal supramolecular entities is reported; controlled radical polymerization of styrene using this initiator is demonstrated to generate well-defined heterotelechelic polymers in a one-step procedure.

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