Addukt eines fünfgliedrigen Trischwefeldistickstoffdioxid‐Rings an Titantetrachlorid

Adduct of a Five‐Membered Trisulfurdinitrogen Dioxide Ring with Titanium Tetrachloride Reaction of S 6 N 4 O 4 with TiCl 4 lead to [(S 3 N 2 O 2 )TiCl 4 ] 2 ( 2 ). Single crystals of 2 were obtained by recrystallization from liquid SO 2 . 2 forms chains of five‐membered S 3 N 2 O 2 rings connected by Ti 2 Cl 8 units. The S 2 N 2 part of the five‐membered ring may be described as a 6‐π electron system.