A fluorescent molecular thermometer based on the nickel(II) high-spin/low-spin interconversion

Marianne Engeser; Luigi Fabbrizzi; Maurizio Licchelli; Donatella Sacchi

doi:10.1039/a901931f

Abstract

1 min read

The temperature of a fluid can be measured through a variation of the fluorescence emission intensity of a naphthalene fragment covalently linked to a NiII tetraaza-macrocyclic complex, which undergoes a temperature dependent spin interconversion equilibrium.

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