The title compound, C7H4BrNO3, was isolated as a by-product while attempting to prepare a diselenide. There is a close intramolecular Br⋯O contact [2.984 (2) Å]. The molecules form loosely associated dimers held together by weak intermolecular Br⋯O interactions with the nitro O atoms [Br⋯O = 3.179 (3) Å]. As a result of these interactions, there is also a close Br⋯Br intermolecular contact [3.8714 (6) Å]. In addition, there are weak intermolecular C—H⋯O interactions. The combination of these interactions produces sheets which propagate in the (210) and (\overline{2}10) directions perpendicular to c.
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