1,3‐Bis[tert‐butyl(di‐tert‐butylfluorsilyl)amino]trisulfan – eine Verbindung mit FSiNSSSNSiF‐Helix

Uwe Klingebiel; Frank Pauer; In Memory: G.M. Sheldrick (1942–2025); Dietmar Stalke

doi:10.1002/cber.19911241203

1,3‐Bis[tert‐butyl(di‐tert‐butylfluorsilyl)amino]trisulfan – eine Verbindung mit FSiNSSSNSiF‐Helix

Chemische Berichte 124(12): 2651-2653

Article 1991 English

Abstract

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1,3‐Bis[ tert ‐butyl(di‐ tert ‐butylfluorosilyl)amino]trisulfane – a Compound with FSiNSSSNSiF Helix The lithium derivative of tert ‐butyl(di‐ tert ‐butylfluorosilyl)‐amine ( 1 ) reacts with sulfur or selenium to give the bis[(fluorosilyl)‐amino]di‐ and ‐trisulfanes 2, 3 and ‐selane 4 , respectively. The trisulfane 3 crystallizes from n ‐hexane and exhibits a helical structure (X‐ray analysis).

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ChemInform Abstract: 1,3‐Bis(tert‐butyl(di‐tert‐butylfluorosilyl)amino)trisulfane—A Compound with FSiNSSSNSiF Helix.

U. Klingebiel, Frank Pauer, In Memory: G.M. Sheldrick (1942–2025), D. Stalke

ChemInform

1,3‐Bis[<i>tert</i>‐butyl(di‐<i>tert</i>‐butylfluorsilyl)amino]trisulfan – eine Verbindung mit FSiNSSSNSiF‐Helix

Abstract

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ChemInform Abstract: 1,3‐Bis(tert‐butyl(di‐tert‐butylfluorosilyl)amino)trisulfane—A Compound with FSiNSSSNSiF Helix.