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The site isolation of lanthanide cations (Er3+, Tb3+, and Eu3+) has been achieved through the self-assembly of three convergent polyether dendrons, each with a carboxylate anion focal point, around the central trivalent cation. Evidence for the self-assembly of the dendritic complexes can be obtained by a variety of spectroscopic and other analytical means both in solution and in the solid state. The luminescence properties of these new dendrimers measured both in solution and in the bulk show a dependence of luminescence activity on the size of the dendritic shell. The observed enhancement in luminescence properties can be attributed both to a large antenna effect, involving the nonconjugated phenyl benzyl ether dendrimer framework, and to a shell effect that results from the effective site isolation of each lanthanide cation within a dendritic sphere, preventing their mutual interaction and decreasing their rate of self-quenching. The site isolation afforded by self-assembly and the antenna effect provided by the polyether dendrimer may be of general applicability in the design of energy-harvesting devices and amplifiers for fiber optics.
Abstract : A computer program for earthquake analysis of gravity dams including effects of hydrodynamic interaction is presented. The dam-water system is idealized as two-dimensional in geometry, the material behavior is assumed to be linearly elastic, and the transverse horizontal as well as the vertical component of ground motion are considered. The dam is represented as a finite element system, whereas water in the reservoir is treated as a continum of infinite length in the upstream direction governed by the wave equation. Compressibility of water is considered resulting in governing equations for the dam depending on the excitation frequency. The analysis is performed in the frequency domain, first obtaining the frequency responses and then Fourier Synthesizing them by Fast Fourier Transform procedures to obtain responses to arbitrary ground motion. A listing of the computer program is included and the usage and capabilities are illustrated by examples. (Author)
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.