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We have investigated the transport properties in the direction perpendicular to the substrate of regioregular poly(3-hexyl-thiophene) of different molecular weights (MW) in a diode geometry. In these devices, which exhibit space-charge-limited behavior, we find that the mobility values at room temperature increase from 1.33×10−5cm2∕Vsto3.30×10−4cm2∕Vs as the MW is increased from 2.9to31.1kg∕mol. The mobility is found to be field independent for high MW films, but field dependent for the low MW films. The current–voltage characteristics of the diodes are also studied as a function of temperature from 160Kto300K. The activation energy for carrier transport, extracted from the Arrhenius plot, is found to decrease gradually from 143meVto126meV as the MW is increased.
Sum frequency generation (SFG) surface vibrational spectroscopy and kinetic measurements using gas chromatography have identified at least two reaction pathways for benzene hydrogenation on the Pt(100) and Pt(111) single-crystal surfaces at Torr pressures. Kinetic studies at low temperatures (310-370 K) show that benzene hydrogenation does not proceed through cyclohexene. A Langmuir-Hinshelwood-type rate law for the low-temperature reaction pathway is identified. The rate-determining step for this pathway is the addition of the first hydrogen atom to adsorbed benzene for both single-crystal surfaces, which is verified by the spectroscopic observation of adsorbed benzene at low temperatures on both the Pt(100) and Pt(111) crystal faces. Low-temperature SFG studies reveal chemisorbed and physisorbed benzene on both surfaces. At higher temperatures (370-440 K), hydrogenation of benzene to pi-allyl c-C(6)H(9) is observed only on the Pt(100) surface. Previous single-crystal studies have identified pi-allyl c-C(6)H(9) as the rate-determining step for cyclohexene hydrogenation to cyclohexane.
An Silber gestreut: Polyedrische Silbernanokristalle liefern komplexe und charakteristische Streusignale, die von ihrer Form und Größe bestimmt sind (siehe Bild). Die Fähigkeit, spezifische Plasmon-Moden zu erzeugen, sollte wichtige Auswirkungen für die oberflächenverstärkte Raman-Spektroskopie, die Subwellenlängenoptik und den Transport mithilfe von Plasmonen haben.
Abstract A thin-layer mixed-potential model (TLMPM) is described for calculating redox and corrosion potentials for high-level nuclear waste (HLNV) canisters in a tuff repository. The model assumes that the canister surface covered by a thin liquid (water) layer, which is irradiated by γ-photons from the decay of radionuclides in the waste. The dose rate and the temperature at the surface are assumed to decay exponentially with time. Redox and corrosion potentials are calculated by equating the sum of partial currents for charge-transfer reactions involving various electroactive radiolysis products and the metal substrate to zero. Estimated polarization data for type 304L (UNS S30403) and type 316L (UNS S31603) stainless steels, for alloy 825 (UNS N08825), and for copper alloys CDA 102 (UNS C10200), CDA 613 (UNS C61300), and CDA 715 (UNS C71500) in high-temperature aqueous Solutions were combined with the TLMPM to calculate redox and corrosion potentials over a 1000-year time period. The model predicts th...
Volcanic aerosols from the 1991 Mount Pinatubo eruption greatly increased diffuse radiation worldwide for the following 2 years. We estimated that this increase in diffuse radiation alone enhanced noontime photosynthesis of a deciduous forest by 23% in 1992 and 8% in 1993 under cloudless conditions. This finding indicates that the aerosol-induced increase in diffuse radiation by the volcano enhanced the terrestrial carbon sink and contributed to the temporary decline in the growth rate of atmospheric carbon dioxide after the eruption.
Many public hospitals have adopted Lean management methodology, but little is known about the extent of Lean adoption or the relationship between Lean adoption and hospital performance. Using data from the 2017 National Survey of Lean/Transformational Performance Improvement in Hospitals, linked with data from the American Hospital Association 2015 Annual Hospital Survey and 2015 Centers for Medicare & Medicaid Services data on hospital performance, we compare public hospitals with nonprofit and for-profit hospitals on the rate of Lean adoption and the extent of Lean implementation. We also assess the associations between Lean adoption by the end of 2014 and measures of public hospital financial performance, patient outcomes, and patient satisfaction measured in 2015.Among the 288 public hospitals that responded to the survey, 54.2% reported that they had adopted Lean. The average length of time of Lean implementation was 4.58 years. The mean number of units in which Lean was implemented was 11.9 out of 29 possible hospital units, with the emergency department (ED) being the unit in which Lean was most frequently implemented. The most common Lean practices used were daily huddles, plan-do-study-act cycles, visual management, and use of standard work. Lean adoption by 2014 was significantly associated in the direction predicted with earnings before interest, taxes, depreciation, and amortization margin (b = .042, p < .020) and percentage of patients leaving the ED without being seen (b = -0.610, p < .068). No significant associations were found between Lean adoption and patient outcomes or patient satisfaction.
Abstract Modern surface science techniques have been applied to the heterogeneous Ziegler‐Natta catalysis system, polymerizing α‐olefins to produce polyolefins, and revealed the correlation between the catalyst surface structure and polymer properties. Two types of thin films—TiCl x /MgCl 2 and TiCl y /Au—were fabricated on an inert gold substrate, using chemical vapor deposition methods, to mimic the high‐yield catalysts of MgCl 2 ‐supported TiCl 4 and TiCl 3 ‐based catalysts, respectively. Once activated with triethylaluminum (AlEt 3 ) vapor, both catalysts were active for polymerization of ethylene and propylene in the absence of excess AlEt 3 . The model catalyst films were as active as the high‐surface‐area industrial catalysts. Both catalysts were terminated with chlorine at the surface but had different surface structures. The TiCl x /MgCl 2 film had a distribution of two structures: the dominant sites had the (001) basal plane of these halide crystallites and the minority sites had a non‐basal plane structure. The surface of the TiCl y /Au film assumed only the non‐basal plane structure. These structural differences resulted in different tacticity of the polypropylene produced with these catalysts. The TiCl x /MgCl 2 catalyst produced both atactic and isotactic polypropylene, whereas the TiCl y catalyst without the MgCl 2 support produced exclusively isotactic polypropylene. The titanium oxidation states did not appear to be an important factor in determining the tacticity of the polypropylene. Copyright © 2001 John Wiley & Sons, Ltd.