Publications

Using molecular dynamics simulations, we have studied the atomic correlations characterizing the second peak in the radial distribution function (RDF) of metallic glasses and liquids. The analysis was conducted from the perspective of different connection schemes of atomic packing motifs, based on the number of shared atoms between two linked coordination polyhedra. The results demonstrate that the cluster connections by face-sharing, specifically with three common atoms, are most favored when transitioning from the liquid to glassy state, and exhibit the stiffest elastic response during shear deformation. These properties of the connections and the resultant atomic correlations are generally the same for different types of packing motifs in different alloys. Splitting of the second RDF peak was observed for the inherent structure of the equilibrium liquid, originating solely from cluster connections; this trait can then be inherited in the metallic glass formed via subsequent quenching of the parent liquid through the glass transition, in the absence of any additional type of local structural order. Increasing ordering and cluster connection during cooling, however, may tune the position and intensity of the split peaks.

Supernova (SN) 2005ip was a Type IIn event notable for its sustained strong interaction with circumstellar material (CSM), coronal emission lines and infrared (IR) excess, interpreted as shock interaction with the very dense and clumpy wind of an extreme red supergiant. We present a series of late- time spectra of SN 2005ip and a first radio detection of this SN, plus late-time X-rays, all of which indicate that its CSM interaction is still strong a decade post- explosion. We also present and discuss new spectra of geriatric SNe with continued CSM interaction: SN 1988Z, SN 1993J and SN 1998S. From 3 to 10 yr post- explosion, SN 2005ip's Ha luminosity and other observed characteristics were nearly identical to those of the radio- luminous SN 1988Z, and much more luminous than SNe 1993J and 1998S. At 10 yr after explosion, SN 2005ip showed a drop in Ha luminosity, followed by a quick resurgence over several months. We interpret this Ha variability as ejecta crashing into a dense shell located less than or similar to 0.05 pc from the star, which may be the same shell that caused the IR echo at earlier epochs. The extreme Ha luminosities in SN 2005ip and SN 1988Z are still dominated by the forward shock at 10 yr post- explosion, whereas SN 1993J and SN 1998S are dominated by the reverse shock at a similar age. Continuous strong CSM interaction in SNe 2005ip and 1988Z is indicative of enhanced mass- loss for similar to 10(3) yr before core collapse, longer than Ne, O or Si burning phases. Instead, the episodic mass- loss must extend back through C burning and perhaps even part of He burning.

Abstract It is well known that massive stars ( M > 8 M ☉ ) evolve up to the collapse of the stellar core, resulting in most cases in a supernova (SN) explosion. Their heterogeneity is related mainly to different configurations of the progenitor star at the moment of the explosion and to their immediate environments. We present photometry and spectroscopy of SN 2010bt, which was classified as a Type IIn SN from a spectrum obtained soon after discovery and was observed extensively for about 2 months. After the seasonal interruption owing to its proximity to the Sun, the SN was below the detection threshold, indicative of a rapid luminosity decline. We can identify the likely progenitor with a very luminous star (log L / L ☉ ≈ 7) through comparison of Hubble Space Telescope images of the host galaxy prior to explosion with those of the SN obtained after maximum light. Such a luminosity is not expected for a quiescent star, but rather for a massive star in an active phase. This progenitor candidate was later confirmed via images taken in 2015 (∼5 yr post-discovery), in which no bright point source was detected at the SN position. Given these results and the SN behavior, we conclude that SN 2010bt was likely a Type IIn SN and that its progenitor was a massive star that experienced an outburst shortly before the final explosion, leading to a dense H-rich circumstellar environment around the SN progenitor.

Abstract The title reactions occur with a variety of aliphatic, aryl, and heteroaryl allylic benzoates to form the corresponding allylic substitution products in high yields with good to excellent enantioselectivity with a scope that encompasses a range of anionic carbon and heteroatom nucleophiles.

This paper describes how building designers make sense of the sky and modern visualization techniques for representing them.The dialectic approach addresses technological innovation with respect to existing social practices.This is done for two reasons-to illustrate where practices are and how they can be extended with innovative technologies.It is shown that building designers maintain various levels of expertise for managing daylight design.Visualization prototypes are introduced also with different degrees of precision.The paper concludes with implications for the development of design tools and use by building designers.

A cobalt-sulfide (Co-S) film prepared via electrochemical deposition on conductive substrates is shown to behave as an efficient and robust catalyst for electrochemical and photoelectrochemical hydrogen generation from neutral pH water. Electrochemical experiments demonstrate that the film exhibits a low catalytic onset overpotential (η) of 43 mV, a Tafel slope of 93 mV/dec, and near 100% Faradaic efficiency in pH 7 phosphate buffer. Catalytic current densities can approach 50 mA/cm(2) and activity is maintained for at least 40 h. The catalyst can also be electrochemically coated on silicon, rendering a water-compatible photoelectrochemical system for hydrogen production under simulated 1 sun illumination. The facile preparation of this Co-S film, along with its low overpotential, high activity, and long-term aqueous stability, offer promising features for potential use in solar energy applications.

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

Abstract Purpose This study sought to identify the organizational factors associated with team and network effectiveness of the Athena Breast Health Network, a multi-site collaboration between five University of California health systems. Design/methodology/approach Providers, managers, and support staff completed self-administered surveys over three years. Statistical analyses at the network and medical center levels tested hypotheses regarding the correlates of effective teams and perceived network effectiveness over time. Findings Perceived team effectiveness was positively correlated with group culture and environments which support collaboration, negatively correlated with hierarchical culture, and negatively associated with professional tenure at year two. As measured by increasing team effectiveness scores over time and Athena’s potential impact on patient care, perceived network effectiveness was positively associated with team effectiveness. Research limitations/implications Results do not allow us to conclude that a certain type of culture “causes” team effectiveness or that team effectiveness “causes” greater perceptions of progress over time. Subsequent studies should examine these variables simultaneously. Further research is needed to examine the role of payment incentives, internal reward systems, the use of electronic health records, public disclosure of performance data, and depth of leadership within each organization and within the network overall. Practical implications Focusing on group affiliation and participation may improve team member perceptions regarding effectiveness and impact on patient care. Originality/value Relatively little is known about the adaptive processes that occur within inter-organizational networks to achieve desired goals, and particularly the roles played by multi-disciplinary inter-professional teams. We studied a network comprising multiple campuses actively involved in better understanding, preventing, and treating a complex disease.

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.