Abstract : Nonfluorinated proton conducting superionic molecular tunnel electrolytes (PSMTE) exhibiting high proton conductivity (approximately 10 exp-2 S/cm) have been synthesized. The highly hygroscopic nature of these polymers yielding deliquescent films has precluded their use in supercapacitors. Fluorinated analogs of these PSMTE's were synthesized to provide higher conductivity and greater hydrophobicity. Fluorinated PSMTE's exhibit higher conductivity than Nafion (1.3 x 10 exp-2 vs. 2.1 x 10 exp-4 S/cm) under identical conditions of relative humidity and temperature. Fluorinated PSMTE's show good film forming properties suitable for fabrication of supercapacitors. However, these materials have not yet been utilized in supercapacitors. Polymer films of aniline and its various derivatives having electron donating (-OCH3) and electron withdrawing groups (-SO3H, -NO2) were formed electrochemically using platinum and nickel substrates. These films were characterized by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The electron withdrawing groups (-SO3H, -NO2) increased the voltage at which the redox reaction occurs for aniline. The electron donating groups (-OCH3) moved the redox potential in the negative direction. The monomers were also deposited on Nafion coated Pt. These films gave multiple oxidation-reductions peaks and better discharge characteristics as compared to films on bare Pt. They also exhibited electrochromic behavior. To demonstrate 'proof of concept,' different combinations of the polymers and Pt black were used as electrodes with a thin (0.001 in.) Nafion membrane to form a capacitor/battery. The capacity and the energy density were determined for the cells. The cells were able to pulse charge-discharge for times as low as 0.1 ms.
Abstract Review: 77 refs.
The last 20 years of metabolic engineering has enabled bio-based production of fuels and chemicals from renewable carbon sources using cost-effective bioprocesses. Much of this work has been accomplished using engineered microorganisms that act as chemical factories. Although the time required to engineer microbial chemical factories has steadily decreased, improvement is still needed. Through the development of synthetic biology tools for key microbial hosts, it should be possible to further decrease the development times and improve the reliability of the resulting microorganism. Together with continuous decreases in price and improvements in DNA synthesis, assembly and sequencing, synthetic biology tools will rationalize time-consuming strain engineering, improve control of metabolic fluxes, and diversify screening assays for cellular metabolism. This review outlines some recently developed synthetic biology tools and their application to improve production of chemicals and fuels in yeast. Finally, we provide a perspective for the challenges that lie ahead.
DFM thanks NERC for continued funding of the Argon Isotope Facility at SUERC and NERC Faciltiies grant IP/1626/0516. PRR thanks the Ann and Gordon Getty Foundation and the U.S. National Science Foundation (grant BCS-0715465) for support of his work. LM was funded by the Marie Curie FP7 Intra-European Fellowship Program for the duration of this project. VCS acknowledges support from the John Fell Fund, University of Oxford.
This book contains the proceedings of a symposium sponsored by the Structural Materials, Physical Metallurgy, and Mechanical Metallurgy Committee of The Metallurgical Society. Some of the titles of the papers include: Fundamentals of Fracture and Fatigue: A Basis for Alloy Design, The Design of Tough Ferritic Steels for Cryogenic Use, Grain Boundary Segregation and Environmentally Induced Fracture Materials, and The Design of Low-Alloy Steels for Thick-Wall Pressure Vessels.