A rare, structurally characterized μ1,η1-hydrazonato complex is a probable intermediate in the Pd-catalyzed N-arylation of hydrazones. Starting from aryl halides the reaction proceeds efficiently and under mild conditions with chelating phosphane ligands (L2); even Cs2CO3 can be used as the base [Eq. (a)]. R=alkyl, aryl, MeCO, MeO; X=Br, I.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDirected Transformation of Molecules to Solids: Synthesis of a Microporous Sulfide from Molecular Germanium Sulfide CagesO. M. Yaghi, Z. Sun, D. A. Richardson, and T. L. GroyCite this: J. Am. Chem. Soc. 1994, 116, 2, 807–808Publication Date (Print):January 1, 1994Publication History Published online1 May 2002Published inissue 1 January 1994https://doi.org/10.1021/ja00081a067RIGHTS & PERMISSIONSArticle Views1404Altmetric-Citations244LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (297 KB) Get e-AlertscloseSupporting Info (2)»Supporting Information Supporting Information Get e-Alerts
In this perspective, we take a critical look at the research progress within the nanowire community for the past decade. We discuss issues on the discovery of fundamentally new phenomena versus performance benchmarking for many of the nanowire applications. We also notice that both the bottom-up and top-down approaches have played important roles in advancing our fundamental understanding of this new class of nanostructures. Finally we attempt to look into the future and offer our personal opinions on what the future trends will be in nanowire research.
Some implants have approximately a lifetime of 15 years. The femoral stem,\nfor example, should be made of 316L/316LN stainless steel. Fretting corrosion,\nfriction under small displacements, should occur during human gait, due to\nrepeated loadings and un-loadings, between stainless steel and bone for\ninstance. Some experimental investigations of fretting corrosion have been\npracticed. As well known, metallic alloys and especially stainless steels are\ncovered with a passive film that prevents from the corrosion and degradation.\nThis passive layer of few nanometers, at ambient temperature, is the key of our\ncivilization according to some authors. This work is dedicated to predict the\npassive layer thicknesses of stainless steel under fretting corrosion with a\nspecific emphasis on the role of proteins. The model is based on the Point\nDefect Model (micro scale) and an update of the model on the friction process\n(micro-macro scale). Genetic algorithm was used for finding solution of the\nproblem. The major results are, as expected from experimental results, albumin\nprevents from degradation at the lowest concentration of chlorides; an\nincubation time is necessary for degrading the passive film; under fretting\ncorrosion and high concentration of chlorides the passive behavior is\nannihilated.\n
We show that two coupled chaotic systems initially operating on two different simultaneously co-existing attractors can be synchronized. Synchronization is achieved as one of the systems switches its evolution to the attractor of the other one. The final attractor of the synchronized state strongly depends on the precise position of trajectories on their attractors at the moment when coupling is introduced. Our system is the first reported example of locally-intermingled basins of attraction which occur in physical systems.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructure sensitivity of catalytic reactionsGabor A. Somorjai and Jose CarrazzaCite this: Ind. Eng. Chem. Fundamen. 1986, 25, 1, 63–69Publication Date (Print):February 1, 1986Publication History Published online1 May 2002Published inissue 1 February 1986https://pubs.acs.org/doi/10.1021/i100021a009https://doi.org/10.1021/i100021a009research-articleACS PublicationsRequest reuse permissionsArticle Views2747Altmetric-Citations143LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access options Get e-Alerts