Compressed sensing has become a widely accepted paradigm to construct high dimensional cluster expansion models used for statistical mechanical studies of atomic configuration in complex multicomponent crystalline materials. However, strict sampling requirements necessary to obtain minimal coherence measurements for compressed sensing to guarantee accurate estimation of model parameters are difficult and in some cases impossible to satisfy due to the inability of physical systems to access certain configurations. Nevertheless, the dependence of energy on atomic configuration can still be adequately learned without these strict requirements by using compressed sensing by way of coherent measurements using redundant function sets known as frames. We develop a particular frame constructed from the union of all occupancy-based cluster expansion basis sets. We illustrate how using this highly redundant frame yields sparse expansions of the configuration energy of complex oxide materials that are competitive and often surpass the prediction accuracy and sparsity of models obtained from standard cluster expansions.
Remembering a lot of things at the same time is difficult. As an experiment, read these numbers: 07041776. Then, close your eyes and try to say them aloud, in order. How did you do? We would guess that you remembered around half of the numbers. Now, try again but think of the same numbers as a date: 07-04-1776. Did you remember more of the numbers this time? You just demonstrated something called working memory. Working memory (“WM” for short) is the ability to hold onto and process pieces of information. WM activates when you experience and remember events in your life, learn new facts, talk to people, read, and do math. WM is a basic human behavior. As shown in the numbers experiment, WM has limited capacity. How does the brain support WM? And, what is happening in the brain that limits our capacity to store multiple memories at the same time?
Using international data starting in 1957, we construct a sample of cases where fast-growing economies slow down. The evidence suggests that rapidly growing economies slow down significantly, in the sense that the growth rate downshifts by at least 2 percentage points, when their per capita incomes reach around US$ 17,000 in year-2005 constant international prices, a level that China should achieve by or soon after 2015. Among our more provocative findings is that growth slowdowns are more likely in countries that maintain undervalued real exchange rates.
The literature currently provides two ways to establish point correspondences between images with moving objects. On one side, there are energy minimization methods that yield very accurate, dense flow fields, but fail as displacements get too large. On the other side, there is descriptor matching that allows for large displacements, but correspondences are very sparse, have limited accuracy, and due to missing regularity constraints there are many outliers. In this paper we propose a method that can combine the advantages of both matching strategies. A region hierarchy is established for both images. Descriptor matching on these regions provides a sparse set of hypotheses for correspondences. These are integrated into a variational approach and guide the local optimization to large displacement solutions. The variational optimization selects among the hypotheses and provides dense and subpixel accurate estimates, making use of geometric constraints and all available image information.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
The present invention is directed to a process for addition of amines to carbon-carbon double bonds in a substrate, comprising: reacting an amine with a compound containing at least one carbon-carbon double bond in the presence a transition metal catalyst under reaction conditions effective to form a product having a covalent bond between the amine and a carbon atom of the former carbon-carbon double bond. The transition metal catalyst comprises a Group 8 metal and a ligand containing one or more 2-electron donor atoms. The present invention is also directed to enantioselective reactions of amine compounds with compounds containing carbon-carbon double bonds, and a calorimetric assay to evaluate potential catalysts in these reactions.
Our website uses cookies to enhance your experience. By continuing to use our site, or clicking "Continue," you are agreeing to our Cookie Policy | Continue JAMA HomeNew OnlineCurrent IssueFor Authors Publications JAMA JAMA Network Open JAMA Cardiology JAMA Dermatology JAMA Health Forum JAMA Internal Medicine JAMA Neurology JAMA Oncology JAMA Ophthalmology JAMA Otolaryngology–Head & Neck Surgery JAMA Pediatrics JAMA Psychiatry JAMA Surgery Archives of Neurology & Psychiatry (1919-1959) Podcasts Clinical Reviews Editors' Summary Medical News Author Interviews More JN Learning / CMESubscribeJobsInstitutions / LibrariansReprints & Permissions Terms of Use | Privacy Policy | Accessibility Statement 2023 American Medical Association. All Rights Reserved Search All JAMA JAMA Network Open JAMA Cardiology JAMA Dermatology JAMA Forum Archive JAMA Health Forum JAMA Internal Medicine JAMA Neurology JAMA Oncology JAMA Ophthalmology JAMA Otolaryngology–Head & Neck Surgery JAMA Pediatrics JAMA Psychiatry JAMA Surgery Archives of Neurology & Psychiatry Input Search Term Sign In Individual Sign In Sign inCreate an Account Access through your institution Sign In Purchase Options: Buy this article Rent this article Subscribe to the JAMA journal
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
Abstract High‐quality wurtzite In‐rich In 1− x Ga x N (0 ≤ x ≤ 0.5) and In 1− y Al y N films (0 ≤ y ≤ 0.25) were grown on sapphire substrates by molecular‐beam epitaxy. Optical absorption, photoluminescence and photomodulated reflectance measurements demonstrate that the fundamental bandgap for InN is only about 0.7 eV. The free electron effective mass is found to vary with free electron concentration, the consequence of a strongly non‐parabolic conduction band caused by the k · p interaction with the valence bands across the narrow bandgap. The bandgap gradually increases with increasing Ga or Al content in In 1− x Ga x N or In 1− y Al y N alloys. The composition dependencies of the bandgaps are well described by bowing parameters of 1.4 eV for In 1− x Ga x N and 3.0 eV for In 1− y Al y N. The direct gaps of the group III‐nitride alloy system cover a very broad spectral range from the near‐infrared in InN to deep‐ultraviolet in AlN. This offers unique opportunities for the use of these alloys in a wide range of optoelectronic and photovoltaic devices. (© 2003 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
