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The CPSNS has used the assessment rubric to create an online resource to inform medical colleague assessment and enhance the usefulness of their NSPAR scores. Further research will be required to determine its impact.
To get predictions from theoretical models of complex mechanical systems, the numerical tools are essential, as very few results can be obtained using analytical methods, especially when large deformations are involved. Variational methods are the preferred (or probably the most powerful) tool to formulate the numerical codes to be used, also in the study of metamaterials. A presentation focused on some aspects of numerical techniques, relevant to the considered class of problems, is presented.
The disclosure provides for metal catecholate frameworks, and methods of use thereof, including gas separation, gas storage, catalysis, tunable conductors, supercapacitors, and sensors.
Samples of Tertiary gabbro from 24 sites in the Keku Strait, Alaska, help constrain the displacement history of the Alexander terrane. Step heating experiments on a plagioclase separate from these previously undated intrusions indicate a discordant 40 Ar/ 39 Ar age of 23.1 ± 1.7 Ma. The characteristic magnetization resides in magnetite, is easily isolated by thermal and alternating field demagnetization, and has both normal and reversed polarities. The mean paleomagnetic pole, with no structural correction, is latitude 87.1°N, longitude 141.6°E, A 95 = 10.1°, with N = 20 sites. This pole indicates insignificant tectonic displacement (0.5° ± 8.2° southward) and rotation (0.6° ± 15.2° counterclockwise). We therefore conclude that any northward displacement or vertical axis rotation of the Alexander terrane, and/or tilting in the vicinity of the Keku Strait must have occurred before 23 Ma.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOxygen- and carbon-bound ruthenium enolates: migratory insertion, reductive elimination, .beta.-hydrogen elimination, and cyclometalation reactionsJohn F. Hartwig, Robert G. Bergman, and Richard A. AndersenCite this: Organometallics 1991, 10, 9, 3326–3344Publication Date (Print):September 1, 1991Publication History Published online1 May 2002Published inissue 1 September 1991https://pubs.acs.org/doi/10.1021/om00055a060https://doi.org/10.1021/om00055a060research-articleACS PublicationsRequest reuse permissionsArticle Views826Altmetric-Citations70LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-AlertscloseSupporting Info (1)»Supporting Information Supporting Information Get e-Alerts
Summary This study develops a framework to evaluate ground motion selection and modification (GMSM) procedures. The context is probabilistic seismic demand analysis, where response history analyses of a given structure, using ground motions determined by a GMSM procedure, are performed in order to estimate the seismic demand hazard curve (SDHC) for the structure at a given site. Currently, a GMSM procedure is evaluated in this context by comparing several resulting estimates of the SDHC, each derived from a different definition of the conditioning intensity measure (IM). Using a simple case study, we demonstrate that conclusions from such an approach are not always definitive; therefore, an alternative approach is desirable. In the alternative proposed herein, all estimates of the SDHC from GMSM procedures are compared against a benchmark SDHC, under a common set of ground motion information. This benchmark SDHC is determined by incorporating a prediction model for the seismic demand into the probabilistic seismic hazard analysis calculations. To develop an understanding of why one GMSM procedure may provide more accurate estimates of the SDHC than another procedure, we identify the role of ‘IM sufficiency’ in the relationship between (i) bias in the SDHC estimate and (ii) ‘hazard consistency’ of the corresponding ground motions obtained from a GMSM procedure. Finally, we provide examples of how misleading conclusions may potentially be obtained from erroneous implementations of the proposed framework. Copyright © 2014 John Wiley & Sons, Ltd.
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Abstract Bis vor kurzem ging Ammoniak nur selten katalytische Transformationen in Gegenwart von Homogenkatalysatoren ein, und die Entwicklung derartiger Reaktionen, die unter milden Bedingungen selektiv nur ein Produkt ergeben, ist auf vielzählige Hindernisse gestoßen. Kürzlich entwickelte Katalysatoren ermöglichen es nun, über verschiedenartige Reaktionen Produkte mit stickstoffhaltigen funktionellen Gruppen aus Ammoniak herzustellen. Diese Reaktionen umfassen Hydroaminomethylierungen, reduktive Aminierungen, Alkylierungen, allylische Substitutionen, Hydroaminierungen und Kreuzkupplungen. Dieser Kurzaufsatz präsentiert Beispiele für solche Reaktionen ebenso wie die Faktoren, die die Katalysatoraktivität und ‐selektivität steuern.
To assist in the development of machine learning methods for automated classification of spectroscopic data, we have generated a universal synthetic dataset that can be used for model validation. This dataset contains artificial spectra designed to represent experimental measurements from techniques including X-ray diffraction, nuclear magnetic resonance, and Raman spectroscopy. The dataset generation process features customizable parameters, such as scan length and peak count, which can be adjusted to fit the problem at hand. As an initial benchmark, we simulated a dataset containing 35,000 spectra based on 500 unique classes. To automate the classification of this data, eight different machine learning architectures were evaluated. From the results, we shed light on which factors are most critical to achieve optimal performance for the classification task. The scripts used to generate synthetic spectra, as well as our benchmark dataset and evaluation routines, are made publicly available to aid in the development of improved machine learning models for spectroscopic analysis.