Publications

Peer-to-peer (p2p) file sharing systems are characterized by highly replicated content distributed among nodes with enormous aggregate resources for storage and communication. These properties alone are not sufficient, however, to render p2p networks immune to denial-of-service (DoS) attack. In this paper, we study, by means of analytical modeling and simulation, the resilience of p2p file sharing systems against DoS attacks, in which malicious nodes respond to queries with erroneous responses. We consider the filetargeted attacks in current use in the Internet, and we introduce a new class of p2p-network-targeted attacks. In file-targeted attacks, the attacker puts a large number of corrupted versions of a single file on the network. We demonstrate that the effectiveness of these attacks is highly dependent on the clients’ behavior. For the attacks to succeed over the long term, clients must be unwilling to share files, slow in removing corrupted files from their machines, and quick to give up downloading when the system is under attack. In network-targeted attacks, attackers respond to queries for any file with erroneous information. Our results indicate that these attacks are highly scalable: increasing the number of malicious nodes yields a hyperexponential decrease in system goodput, and a moderate number of attackers suffices to cause a near-collapse of the entire system. The key factors inducing this vulnerability are (i) hierarchical topologies with misbehaving “supernodes,” (ii) high path-length networks in which attackers have increased opportunity to falsify control information, and (iii) power-law networks in which attackers insert themselves into high-degree points in the graph. Finally, we consider the effects of client counter-strategies such as randomized reply selection, redundant and parallel download, and reputation systems. Some counter-strategies (e.g., randomized reply selection) provide considerable immunity to attack (reducing the scaling from hyperexponential to linear), yet significantly hurt performance in the absence of an attack. Other counter-strategies yield little benefit (or penalty). In particular, reputation systems show little impact unless they operate with near perfection.

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

Abstract [Mn 4 O 4 {O 2 P(O t Bu) 2 } 6 ] ( 1 ), an Mn 4 O 4 cubane complex combining the structural inspiration of the photosystem II oxygen‐evolving complex with thermolytic precursor ligands, was synthesized and fully characterized. Core oxygen atoms within complex 1 are transferred upon reaction with an oxygen‐atom acceptor (PEt 3 ), to give the butterfly complex [Mn 4 O 2 {O 2 P(O t Bu) 2 } 6 (OPEt 3 ) 2 ]. The cubane structure is restored by reaction of the latter complex with the O‐atom donor PhIO. Complex 1 was investigated as a precursor to inorganic Mn metaphosphate/pyrophosphate materials, which were studied by X‐ray absorption spectroscopy to determine the fate of the Mn 4 O 4 unit. Under the conditions employed, thermolyses of 1 result in reduction of the manganese to Mn II species. Finally, the related butterfly complex [Mn 4 O 2 {O 2 P(pin)} 6 (bpy) 2 ] (pin=pinacolate) is described.

Rod MOFs are metal-organic frameworks in which the metal-containing secondary building units consist of infinite rods of linked metal-centered polyhedra. For such materials, we identify the points of extension, often atoms, which define the interface between the organic and inorganic components of the structure. The pattern of points of extension defines a shape such as a helix, ladder, helical ribbon, or cylinder tiling. The linkage of these shapes into a three-dimensional framework in turn defines a net characteristic of the original structure. Some scores of rod MOF structures are illustrated and deconstructed into their underlying nets in this way. Crystallographic data for all nets in their maximum symmetry embeddings are provided.

True n-type doping of titanium oxide without formation of midgap states would expand the use of metal oxides for charge-based devices. We demonstrate that plasma-assisted fluorine insertion passivates defect states and that fluorine acts as an n-type donor in titanium oxide. This enabled us to modify the Fermi level and transport properties of titanium oxide outside the limits of O vacancy doping. The origin of the electronic structure modification is explained by ab initio calculation.

We present the results of spectroscopic observations from the ESSENCE high-redshift supernova (SN) survey during its first four years of operation. This sample includes spectra of all SNe Ia whose light curves were presented by Miknaitis et al. (2007) and used in the cosmological analyses of Davis et al. (2007) and Wood-Vasey et al. (2007). The sample represents 273 hours of spectroscopic observations with 6.5 - 10-m-class telescopes of objects detected and selected for spectroscopy by the ESSENCE team. We present 174 spectra of 156 objects. Combining this sample with that of Matheson et al. (2005), we have a total sample of 329 spectra of 274 objects. From this, we are able to spectroscopically classify 118 Type Ia SNe. As the survey has matured, the efficiency of classifying SNe Ia has remained constant while we have observed both higher-redshift SNe Ia and SNe Ia farther from maximum brightness. Examining the subsample of SNe Ia with host-galaxy redshifts shows that redshifts derived from only the SN Ia spectra are consistent with redshifts found from host-galaxy spectra. Moreover, the phases derived from only the SN Ia spectra are consistent with those derived from light-curve fits. By comparing our spectra to local templates, we find that the rate of objects similar to the overluminous SN 1991T and the underluminous SN 1991bg in our sample are consistent with that of the local sample. We do note, however, that we detect no object spectroscopically or photometrically similar to SN 1991bg. Although systematic effects could reduce the high-redshift rate we expect based on the low-redshift surveys, it is possible that SN 1991bg-like SNe Ia are less prevalent at high redshift.