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Born and raised in a remote mountain village of the Pyrénées in southwestern France, Pierre Bourdieu moved to Paris in the early 1950s to study at the prestigious Ecole Normale Supérieure at a time when philosophy was the queen discipline and the obligatory vocation of any aspiring intellectual. There he quickly grew dissatisfied with the 'philosophy of the subject' exemplified by Sartrian existentialism — then the reigning doctrine — and gravitated toward the 'philosophy of the concept' associated with the works of epistemologists Gaston Bachelard, Georges Canguilhem, and Jules Vuillemin, as well as to the phenomenology of Edmund Husserl and Maurice Merleau-Ponty. Shortly after graduation, however, Bourdieu forsook a projected study of affective life mating philosophy, medicine, and biology and, as other illustrious normaliens such as Durkheim and Foucault had done before him, he converted to social science.
An enantioselective gold(I)-catalyzed intramolecular [4 + 2]-cycloaddition of allenes and dienes is reported. The reactions allow for the asymmetric synthesis of trans-hexahydroindenes and pyrrolidine products using C(3)-symmetric phosphitegold(I) and ortho-arylphosphoramiditegold(I) complexes as catalysts, respectively.
A comparison of the structure, spectroscopy, and oxygen atom-transfer reactivity of cofacial bisporphyrins anchored by xanthene (DPX) and dibenzofuran (DPD) pillars is presented. The synthesis and characterization of dicopper(II) and dinickel(II) complexes of DPD completes a homologous series of homobimetallic zinc(II), copper(II), and nickel(II) complexes for both cofacial platforms. X-ray crystallographic analysis of the parent free-base porphyrins H(4)DPX (1) and H(4)DPD (5) confirms the face-to-face arrangement of the two porphyrin macrocycles with a large available range of vertical pocket sizes: 1 (C(80)H(92)Cl(2)N(8)O), triclinic, space group P1 macro, a = 13.5167(12) A, b = 21.7008(18) A, c = 23.808(2) A, alpha = 80.116(2) degrees, beta = 76.832(2) degrees, gamma = 80.4070(10) degrees, Z = 4; 5 (C(80)H(83)N(8)O(2)), monoclinic, space group C2/c, a = 22.666(2) A, b = 13.6749(14) A, c = 42.084(4) A, beta = 94.554(2) degrees, Z = 8. EPR spectroscopy of dicopper(II) derivatives Cu(2)DPX (3) and Cu(2)DPD (7) complements the crystallographic studies by probing intramolecular metal-metal arrangements in frozen solution. Exciton interactions between the porphyrin subunits in fluid solution are revealed by steady-state and time-resolved electronic absorption and emission spectroscopy. The resulting compilation of structural and spectroscopic data provides a benchmark for the use of these and related platforms for the activation of small-molecule substrates. A structure-function relation is developed for the photoinduced oxygen atom-transfer reactions of bisiron(III) mu-oxo derivatives of DPX and DPD. The efficiency of the photochemical process is markedly dependent (approximately 10(4)-fold) on the vertical flexibility of cofacial architecture provided by the spacer.
Abstract For Abstract see ChemInform Abstract in Full Text.
— Cyclic fatigue‐crack growth and resistance‐curve behavior have been studied in a fine‐grained (∼ 1 μm), high‐purity alumina. Specific emphasis is given to the mechanisms associated with crack growth that are controlled by the maximum ( K max ) and the alternating (Δ K ), stress intensities and to the role of crack‐face interference (crack closure), which is known to be an important crack‐tip shielding mechanism in metal fatigue. Significant levels of subcritical crack growth were detected above a threshold stress intensity of ∼60% of the fracture toughness ( K c ) in the alumina, with growth rates displaying a far larger dependence on K max compared to Δ K. The role of crack closure was examined using constant‐ K max experiments, where the minimum stress intensity ( K min ) was maintained either above or below the stress intensity for crack closure ( K cl ). Where K min < K cl , growth rates were found to exhibit a lower dependence on Δ K , which was rationalized in terms of the frictional wear model for crack growth in grain‐bridging ceramics. It is concluded that crack closure, as conventionally defined, has little relevance as a crack‐tip shielding mechanism during fatigue‐crack growth in grain‐bridging ceramics, due to the low dependence of growth rates on Δ K compared to K max .
The quality of algae as food for larval Pacific treefrogs, Hyla regilla, varies among algal taxa. Tadpole diets were manipulated in enclosures in the South Fork Eel River, northern California. Enclosed tadpoles were fed ad libitum one of the dominant filamentous green algae (Cladophora, Zygnema, Mougeotia, or Oedogonium), the dominant cyanobacterium in the habitat (Nostoc), flocculent detritus, or a commercial reptile/amphibian food. Tadpoles in a control treatment were not fed but had access to seston which deposited in all enclosures. Diet treatment significantly affected weekly growth rates, as well as time to and weight at metamorphosis. Tadpoles grew most rapidly on filamentous green algae with diatom epiphytes and on the commercial food. Tadpoles fed epiphytized Cladophora metamorphosed 27.1% (11.7 days) sooner and weighed 38.9% (70 mg) more than tadpoles fed Cladophora cleaned of diatoms. In comparison to tadpoles fed Mougeotia, which does not support epiphytes, tadpoles fed epiphytized Cladophora metamorphosed 37.4% (19.7 days) sooner and weighed 31.6% (50 g) more. Tadpoles with the lowest growth rates were those filtering deposited seston or flocculent detritus. Observed changes in life-history traits with diet are assessed in relation to models which predict the optimal timing of metamorphosis.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.