A highly efficient sp² C-H amination using oxime esters is presented. The reaction is proposed to proceed via oxidative addition of the Pd(0) species into the N-O bond. Strong evidence is provided by an isolated Pd(II) complex generated from oxidative addition of Pd(0) into the N-O bond.
Self-phase modulation in a ${\mathrm{CO}}_{2}$-laser breakdown plasma is observed to down-shift the wavelength from 10.6 to about 10.0 \ensuremath{\mu}m. This results from the sudden drop in refractive index, from 1 to 0, which accompanies the ionization of the gas. The pressure dependence of this effect in nitrogen is opposite to that in helium.
ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTRegiodefined Poly(N-arylaniline)s and Donor−Acceptor Copolymers via Palladium-Mediated Amination ChemistryFelix E. Goodson and John F. HartwigView Author Information Department of Chemistry, Yale University, P.O. Box 208107, New Haven, Connecticut 06520-8107 Cite this: Macromolecules 1998, 31, 5, 1700–1703Publication Date (Web):February 19, 1998Publication History Received7 January 1998Published online19 February 1998Published inissue 1 March 1998https://pubs.acs.org/doi/10.1021/ma980027rhttps://doi.org/10.1021/ma980027rrapid-communicationACS PublicationsCopyright © 1998 American Chemical SocietyRequest reuse permissionsArticle Views673Altmetric-Citations61LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-AlertscloseSupporting Info (1)»Supporting Information Supporting Information SUBJECTS:Group 15 compounds,Materials,Monomers,Polymerization,Polymers Get e-Alerts
We describe a new control method for vibrations-based planar manipulation. We've developed a device-the Universal Planar Manipulator (UPM)-based on a single, horizontally-vibrating plate. Though minimalist in construction (one moving part), the UPM can manipulate several parts on its surface in parallel, simply using friction. The authors previously showed (1998) that a sequence of rigid plate rotations can be computed which produces pre-specified part displacements. Here we present a new method based on a special motion primitive-the "jet"-which displaces a chosen part in a desired direction while keeping all others still. Parallel manipulation then reduces to a round-robin application of jets. This technique is both faster and more robust than the old rotations-based method. Experiments on parallel trajectory following and part sorting are presented. With jets, the UPM becomes a practical technology for applications such as part singulation, feeding, sorting, food handling, product displays, and interactive devices such as active desks and toys.
A quasichemical method that combines ab initio treatment of explicit solvent with dielectric continuum models has been used to study the origin of a strong effect of methanol on the extent of iron(III) [tetrakis(pentafluorophenyl)]porphyrin chloride dissociation in acetonitrile-methanol solutions. It is shown that the dissociation is energetically more favorable in methanol than in acetonitrile primarily because of the strong specific interactions between the chloride anion and the solvent methanol molecules in its first solvation shell. These interactions are weaker in acetonitrile. The final estimate for the difference in the dissociation free energies in methanol and acetonitrile is -23 kJ/mol, in a good agreement with the experimental value of -21 kJ/mol. Energy decomposition analysis of chloride-solvent interactions suggests that stronger chloride-methanol binding is a result of the contribution of charge delocalization effects to the chloride-methanol interactions.
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La gestion de la innovacion para obtener beneficios es una cuestion compleja. No obstante, algunos enfoques pueden ayudar a los directivos a la hora de centrarse en lo basico. Las acciones de gestion, tanto si proceden de empresas grandes como si proceden de empresas pequenas, en diversas ocasiones pueden configurar el papel de la propiedad intelectual y de la propia tecnologia a la hora de definir el sistema de apropiabilidad y la arquitectura del sector. El marco que se desarrolla en este articulo puede permitir tanto a los teoricos como a los directivos considerar la estrategia tecnologica de una forma mas amplia.
The layer-by-layer additive manufacturing approach results in the 3D printed composite lattice structure fails to exploit fiber reinforcement, thereby resulting in inferior mechanical qualities. To address this challenge, this study proposes a novel approach leveraging composite fused filament fabrication (FFF) printing to design modular assembled composite lattice structures. Initially, three high-performance lattice structures were transformed into discrete 2D components and assembled into 3D lattice structures. Subsequently, the mechanical properties of these structures were comprehensively assessed using theoretical, experimental, and finite element analysis methods. Finally, the comparison between the assembled structures and integrated printed lattice structures in terms of surface quality, mechanical properties, and manufacturability revealed significant advantages. The theoretical and finite element analyses accurately predicted the mechanical properties of the lattice structures. The lattice structures that were assembled in a modular way displayed an impressive 74% improvement in surface finish. Additionally, they showed peak strength increases of 140%, 27%, and 26%, respectively, for the mentioned types of topology. The energy absorption also increased significantly by 510.83%, 44.18%, and 30.24%. Furthermore, these assembled structures required less printing support materials, enhancing their manufacturability and cost-effectiveness. This new method of designing modular space structures goes beyond the limitations imposed by equipment by using high-performance topology. It allows for the construction of large-scale, lightweight space structures that offer excellent performance. This study explores innovative opportunities in the field of space manufacturing, offering potential implications for the development of lunar habitats, space telescopes, and space power stations.