Bisphenol A (BPA) is amongst the endocrine disrupting compounds (EDCs) that cause illness to humans and in this work was removed using copper (I) oxide (Cu
Arsenic (As) is a common aquatic pollutant that enters the environment from anthropogenic sources and causes serious public health issues. Various conventional techniques have been applied for As removal from drinking water. However, those conventional techniques could not meet the requirement of the As discharge standard of <10 mg/L in drinking water set by the World Health Organization (WHO). To deal with this bottleneck, membrane distillation (MD) offers a complete As removal from an aqueous solution due to its higher rejection rate with less energy consumption than thermal techniques that require high thermal energy. This article reviews the recent progress of MD configurations, membrane modules, and membrane materials employed for As removal. This work also uncovers the technological solutions of MD in tackling a variety of bottlenecks in removing As from aqueous solutions. This includes integrating MD with alternative energy sources and/or forward osmosis (FO) to incorporate its hybrid systems with less energy consumption or a high separation rate. Limitations, challenges, and opportunities of MD systems for As removal were highlighted with a technological solution to these bottlenecks. The MD systems can effectively remove As (III) and As (V) with 100 % As rejection using hydrophobic ceramic and polymeric membranes. Overall, MD could play a role in helping the water industry meet the United Nations' Sustainable Development Goals (SDGs), such as clean water, affordable energy, and climate change mitigation.
Background The commercialization of mullite-kaolinite hollow fibre HFMs is still obstructed due to the weakness of their mechanical strength. Methods This study investigates the effect of different sintering temperatures (i.e., 1350, 1400, 1450 and 1500 °C) on the mechanical strength and other functional properties of ceramic HFMs composed of mullite-kaolinite and stainless steel (SS). The membranes were tested and evaluated through an oil-in-water separation process using three oily emulsions (i.e. 1000, 1500, and 2000 ppm) in a filtration system for 120 min. Significant findings The results showed a successful preparation for mullite-SS HFMs with asymmetrical and sponge-like structures. Increased sintering temperatures from 1350 to 1500 °C significantly integrated mullite and SS particles, and forming robust bonds improved the mechanical strength. Amongst all mullite-SS HFMs, the membrane sintered at 1450 °C was the most suitable for oil-in-water separation due to its optimum properties compared to other mullite-SS HFMs. As compared to mullite HFMs counterparts, the mullite-SS HFM at 1450 °C exhibited higher mechanical strength, oil rejection rate and permeate flux of 106.4 MPa, 99.05% and 345 L/m2.h, respectively. In addition, it showed higher mechanical stability and separation performance for a longer filtration time of 120 min than other CHFMs prepared from different low-cost materials reported in previous works. This membrane offers an advantage in mechanical strength, water flux, and rejection performance, making it suitable for various water treatment applications.
No abstract is provided for this article.
Biogas upgrading is a widely studied and discussed topic and its utilisation as a natural gas substitute has gained a significant attention in recent years. The production of biomethane provides a versatile application in both heat and power generation and as a vehicular fuel. This paper systematically reviews the state of the art of biogas upgrading technologies with upgrading efficiency, methane (CH4) loss, environmental effect, development and commercialisation, and challenges in terms of energy consumption and economic assessment. The market situation for biogas upgrading has changed rapidly in recent years, making the membrane separation gets significant market share with traditional biogas upgrading technologies. In addition, the potential utilisation of biogas, efficient conversion into bio-compressed natural gas (bio-CNG), and storage systems are investigated in depth. Two storing systems for bio-CNG at filling stations, namely buffer and cascade storage systems are used. The best storage system should be selected on the basis of the advantages of both systems. Also, the fuel economy and mass emissions for bio-CNG and CNG filled vehicles are studied. There is the same fuel economy and less carbon dioxide (CO2) emission for bio-CNG. Based on the results of comparisons between the technical features of upgrading technologies, various specific requirements for biogas utilisation and the relevant investment, and operating and maintenance costs, future recommendations are made for biogas upgrading.
No abstract is provided for this article.
In this work, we develop superhydrophobic ceramic surfaces possessing flower-like hierarchical structures that can resist surface wetting against not only water but also ethylene glycol and palm oil. This can benefit a wide range of potential applications in many ceramic fields. The synergistic strategy to fabricate superhydrophobic ceramic surfaces relies on the construction of hierarchical structures through pre-roughening. Using TiO2 microflowers obtained via a hydrothermal approach and post-fluorinating via surface grafting with 1H,1H,2H,2H-perfluorodecyltriethoxysilane (C8) resulted in better metastable Cassie-Baxter state as water droplet roll-off the surface compared to non-textured ceramic surfaces where the water droplet pinned. The C8-TiO2-modified ceramic surface (C8/TiO2-CRM) can still maintain a high contact angle against palm oil (above nearly 120°) within 40 min of exposure, whereas the un-textured ceramic surface is fully wetted. In addition, the C8/TiO2-CRM has excellent self-cleaning, anti-fouling and “gasphilic” properties. In this work, the robustness of the composite interface from hierarchical structures resulting from TiO2 micro-flowers is further explained.
This work aims to prepare a robust yet low-cost dual-layer hollow fibre ceramic membrane composite membrane (DLZK) fabricated by co-extrusion phase inversion/co-sintering technique to be used in wastewater treatment. The dope suspensions were extruded simultaneously where the outer layer consists of zirconia while the inner layer consists of a mixture of kaolin and zirconia to enhance membrane performance in terms of mechanical strength and wastewater treatment capability. The effects of co-sintering temperature from 1200 to 1500 °C on the membrane’s mechanical strength, porosity, pore size, water permeability, and dissolubility in high alkaline/pH condition were investigated. The membrane performance was evaluated by real wastewater treatment test using two different types of industrial wastewaters which are palm oil mill effluent and textile industry wastewater. The findings show that the proposed method of producing the DLZK membranes could provide good interfacial adhesion and well-dispersed zirconia in the outer layer and the use of kaolin as an alternative natural material for ceramic membrane fabrication. The DLZK co-sintered at 1200 °C had the mechanical strength of 65 MPa, only 3.5 % loss of the original shape in high alkaline solution, and removed almost 95 % for all parameters of COD, TOC, TN, NH3-N and TSS in the both wastewaters suitable for microfiltration purpose.