Among the 3rd generation of photovoltaics (PVs), Cu2ZnSnS4 (CZTS), having the kesterite structure, was one of the most promising absorber layer candidates for low-cost thin-film solar cells. Also, it was composed of earth affluent and non-toxic elements, promising price reductions in prospect compared to CIGS solar cell. However, the common buffer layer for CZTS is Cadmium Sulphate (CdS). The CdS could be replace by a better material, Zinc Tin Oxide. On the other hand, ZnSnO <inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</inf> (ZTO) with several advantages, and the high field-effect electron mobility of ZTO with as high as 20–50 cm2/V s. The master plan was scrutinized opportunity to supersede the default CZTS buffer layer Cadmium Sulphate with Zinc Tin Oxide. In this research, the ZTO layer was deposited on top of the soda-lime glass (SLG). The Zinc Tin Oxide was deposited on top SLG through solution process method. The deposition was tested to show ZTO behavior changes on these layers. Morphological show more tin doped results in bigger grain size. The direct optical band gap of ZTO was calculated to be 2.7 - 3.02 eV.The Zn <inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.867</inf> Sn <inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.133</inf> OCδ shows conductivity of 26µA at 2V.)
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The contribution of palm oil fuel ash (POFA), an agricultural waste as a low cost adsorbent for the removal of arsenite (As(III)) and arsenate (As(V)) was explored. Investigation on the adsorbency characteristics of POFA suspension revealed that the surface area, particle size, composition, and crystallinity of the SiO2 rich mullite structure were the crucial factors in ensuring a high adsorption capacity of the ions. Maximum adsorption capacities of As(III) and As(V) at 91.2 and 99.4 mg g−1, respectively, were obtained when POFA of 30 μm particle size was employed at pH 3 with the highest calcination temperature at 1150 °C. An optimum dosage of 1.0 g of dried POFA powder successfully removed 48.7% and 50.2% of As(III) and As(V), respectively. Molecular modeling using the density functional theory consequently identified the energy for the proposed reaction routes between the SiO− and As + species. The high stability of the POFA suspension in water in conjunction with good adsorption capacity of As(III) and As(V) seen in this study, thus envisages its feasibility as a potential alternative absorbent for the remediation of water polluted with heavy metals.
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In this work, response surface methodology (RSM) was applied for modelling and optimization of operating parameters for water desalination by direct contact membrane distillation (DCMD) system using cost effective and green ceramic hollow fibre membrane prepared from rice husk waste. Operating parameters including feed temperature, permeate temperature and feed flow rate were selected and the optimum parameters were determined for DCMD salt rejection. The developed model for permeate flux response was statistically validated by analysis of variance (ANOVA) which showed a high value coefficient of determination value (R2 = 0.9954). In this study, the obtained optimum operating parameters were found to be 70.15°C of feed temperature, 19.84°C permeate temperature and 0.58 LPM of feed flow rate.
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Dual-layer hollow fiber (DLHF) membranes prepared via a phase inversion based co-extrusion technique offer a number of advantages, such as self-supporting structure, high active surface area to volume ratio, easy fabrication and ability to withstand high operating pressure. This paper reports novel DLHF membranes fabricated via a single step co-extrusion technique with immobilized titanium dioxide (TiO2) nanoparticles embedded in their outer layer. In this work, the DLHF membranes were prepared by extruding two different dope solutions simultaneously, in which the inner layer consisted of poly(vinylidene fluoride) (PVDF) and solvent N,N-dimethylacetamide (DMAc) while the outer layer was a mixture of PVDF, TiO2 and DMAc. The effect of TiO2 loading, where the mass fraction of TiO2/PVDF was varied from 0 to 1, on the morphologies and properties of the DLHF membranes were investigated using scanning electron microscopy (SEM), contact angle goniometer, surface roughness and filtration experiments. The SEM results showed that DLHF membranes have a good interfacial adhesion between layers with no delamination found. The structure of the membranes characterized by the length of their finger-like voids was significantly affected by the TiO2 addition. The void lengths were elongated by the rise of the TiO2 loading up to certain fraction of TiO2/PVDF. Based on all the findings, it can be concluded that the proposed method of producing the DLHF membranes could provide good layer–layer interfacial adhesion and well-dispersed TiO2 in their outer layer.