283 publications from this institution
In this paper, three metal-organic frameworks (Materials of Institut Lavoisier: MILs-100 (Fe)) as porous nanomaterials were synthesized using FeCl3, Fe(NO3)3 and Fe2(SO4)3 and denoted as MIL-100-1, MIL-100-2 and MIL-100-3, respectively. The synthesized MILs-100 (Fe) were characterized by FTIR, SEM, TEM, XRD, UV–vis DRS and zeta potential. Basic Blue 41 (BB41) was used as a model dye to study the photocatalytic dye degradation ability of the synthesized metal organic frameworks. The results showed that the synthesized nanomaterials decolorized BB41. The decolorization kinetics followed first-order kinetic model. The rate constant was 0.0034, 0.0041, 0.0091 and 0.0289 (1/min) for 0.01, 0.02, 0.03 and 0.04 g of photocatalyst. The data indicated that MIL-100-1 had higher photocatalytic activity. The photocatalytic activity of MIL-100 did not decrease significantly for three cycles. It can be concluded that the synthesized MILs-100 (Fe) could be used as alternative catalysts for photocatalytic decolorization of colored wastewater.
The novel fluorescent dyes based on diketopyrrolopyrrole materials were developed as a basic component for use in inkjet ink formulations. N-substituted DPP derivatives of ethyl formate and ethyl acetate (symmetric and asymmetric) were synthesized and characterized. Then, quantum chemical calculations were performed to investigate the observed changes in the photophysical properties of synthesized materials. Photophysical investigations of fluorescence dyes in various solvents and the effect of solvatochromism and the solubility of dyes in inkjet inks and solid state emission of dyes were used to select symmetric and asymmetric derivatives for application in inkjet formulation. In addition, the inkjet ink based on the symmetric N-substituted DPP derivatives of N,N-diethylformate and ethyl acetate was formulated. Inkjet inks were printed on polymeric substrate and their fluorescence were studied. The solubility of the asymmetric N-ethyl acetate dye in ink formulation was lower than symmetric derivatives due to stronger inter-particle interactions. From photophysical features of printed substrate, the final formulation based on symmetric ethyl acetate dye was performed for further investigation. The effect of concentration on the intensity of emission and also on the color properties (Lab) of formulation was studied. The optimum dye concentration of symmetric N,N-diethylacetate dye with highest fluorescent intensity was 0.3wt% in ink formulation. Finally, the symmetric ethyl acetate dyes formulation for security inkjet ink was performed.
