ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis and characterization of new binuclear electron-transfer models containing rigid aromatic spacersYun Kim and Charles M. LieberCite this: Inorg. Chem. 1989, 28, 21, 3990–3992Publication Date (Print):October 1, 1989Publication History Published online1 May 2002Published inissue 1 October 1989https://pubs.acs.org/doi/10.1021/ic00320a010https://doi.org/10.1021/ic00320a010research-articleACS PublicationsRequest reuse permissionsArticle Views124Altmetric-Citations47LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts
This paper describes the use of nanoskiving to fabricate complex metallic nanostructures by sectioning polymer slabs containing small, embedded metal structures. This method begins with the deposition of thin metallic films on an epoxy substrate by e-beam evaporation or sputtering. After embedding the thin metallic film in an epoxy matrix, sectioning (in a plane perpendicular or parallel to the metal film) with an ultramicrotome generates sections (which can be as thin as 50 nm) of epoxy containing metallic nanostructures. The cross-sectional dimensions of the metal wires embedded in the resulting thin epoxy sections are controlled by the thickness of the evaporated metal film (which can be as small as 20 nm) and the thickness of the sections cut by the ultramicrotome; this work uses a standard 45° diamond knife and routinely generates slabs 50 nm thick. The embedded nanostructures can be transferred to, and positioned on, planar or curved substrates by manipulating the thin polymer film. Removal of the epoxy matrix by etching with an oxygen plasma generates free-standing metallic nanostructures. Nanoskiving can fabricate complex nanostructures that are difficult or impossible to achieve by other methods of nanofabrication. These include multilayer structures, structures on curved surfaces, structures that span gaps, structures in less familiar materials, structures with high aspect ratios, and large-area structures comprising two-dimensional periodic arrays. This paper illustrates one class of application of these nanostructures: frequency-selective surfaces at mid-IR wavelengths.
The bifurcation problem of an infinite elastoplastic medium surrounding a spherical cavity and subjected to uniform radial tension or compression at infinity is studied. The material is assumed to be incompressible, and its behaviour is modelled by both hypoelastic (flow theory) and hyperelastic (deformation theory) constitutive relations. No bifurcation was found with the flow theory. Surface bifurcation modes were discovered with the deformation theory in both tension and compression. An independent study is also presented of surface bifurcations of a semi-infinite elastoplastic material under equi-biaxial stress. The critical strain for the half-space coincides with the strain at the spherical cavity at the lowest bifurcation.
Statistical aspects of height of rise and fall in continuous random loading relevant to fatigue failure
Abstract This chapter reviews the links between obesity and individual components of the metabolic syndrome as well as underlying biological mechanisms, such as insulin resistance, systemic inflammation, and endothelial dysfunction. It discusses recent epidemiologic studies on risk of diabetes in relation to changes in fat distribution, the role of overall adiposity versus abdominal obesity, and the relative importance of fatness versus fitness. The chapter also examines epidemiologic literature related to “fellow travelers” of the metabolic syndrome.
OBJECTIVE: Serious defects in social skills acquired during childhood may be associated with aggressive behavior in later life. The authors studied whether being an only child was associated with criminality in adulthood and, secondly, if parental factors increased the putative risk. METHOD: The authors used an unselected, prospectively collected large birth cohort. Data on crimes were linked with being an only child as well as with perinatal risk and maternal and paternal psychological risk factors among male subjects. RESULTS: The risk for violent crimes later in life was elevated among the only children. If perinatal or parental risks were combined with being an only child, the odds ratios for violent offending increased four-fold to eight-fold. A corresponding risk increase between being an only child and nonviolent offending was not detected. CONCLUSIONS: These results support the hypothesis that growing up as an only child is associated with violent criminality among male subjects.
