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Sulfur isotopic composition of dissolved SO(4)(2-) in waters from the Hongfeng and Aha reservoirs and their inflowing tributaries in the Guizhou Province, southwestern China were investigated. The results show that delta(34)S values of SO(4)(2-) range from -6.07 +/- 0.10 parts per thousand to -7.8 +/- 0.01 parts per thousand, with the average SO(4)(2-) concentration of about 0.65 mM/L in the Hongfeng reservoir water but range from -10.00 +/- 0.08 parts per thousand to -10.53 +/- 0.05 parts per thousand, with the average SO(4)(2-) concentration of about 3 mM/L in the Aha reservoir water. delta(34)s values of SO42- in the river water samples from the inflowing tributaries also show relatively low values (-2.34 +/- 0.01 parts per thousand to -11.88 +/- 0.06 parts per thousand) compared to most of river waters of the world. According to the sulfur isotopic compositions and SO(4)(2-) concentrations in the studied reservoir and river waters, three potential sources of dissolved SO(4)(2-), including coal-mining, acid deposition and oxidation of sulfide were identified. Within these S sources, coal mining is the major source of SO(4)(2-) in surface waters of the studied drainage basins. The estimation for the relative contributions of the potential sources indicate that about 80-90% of the sulfate in the Aha reservoir and its inflowing river water and about 60-70% in the Hongfeng reservoir and its inflowing river water are derived from coal strata via the coal mining activities. Acid rainwater and oxidation of sulfide have only limited contributions.
Gold nanorods prepared electrochemically and capped in micelles are examined using high-resolution transmission electron microscopy (TEM). It is found that they have an axial growth direction of [001] and have surfaces made of {100} and the unstable {110} facets. A detailed examination of the defect sites of both of these facets shows that while the defective regions of the stable {100} facets show atom-height steps with no reconstruction, the less stable higher energy {110} surfaces show missing-row reconstruction. The role of micelles in stabilizing the {110} facet in the gold nanorod is briefly discussed.