Tracing the negative resistance characteristics of 2-terminal and 3-terminal devices often ended in failure due to jump phenomenon, hysteresis, and oscillation resulting from the tracing circuit. All of these problems are overcome in the curve tracer described in this paper. A detailed nonlinear dynamic circuit analysis is used to develop a simple method for quenching oscillations and other exotic phenomena. Our curve tracer is designed to trace either voltage-controlled or current-controlled negative resistance characteristics of both 2-terninal and 3-terminal devices. All six representations which completely characterized a 3-terminal or 2-port nonlinear resistor are allowed. In particular, using a novel approach for implementing a nullator and norator, transmission (chain) characteristics of 3-terminal and 2-port devices have been successfully traced for the first time.
A thermodynamic limit of 4n/sup 2/approx. =50 exists for the maximum absorption increase in a randomly textured semiconductor, where n is the semiconductor index of refraction. Optically enhanced solar cells do not achieve this large absorption increase due to parasitic optical absorption by the electrode structure and, scattering properties of surface textures. In this article the authors present a model of absorption enhancement in solar cells which relates independent optical measurements of parasitic absorption and texture performance to measured collection efficiency spectra. Using this model they define limits for short circuit current increases produced by enhancement.
Non-interpenetrating star polymer catalysts designed to mimic the site isolation characteristics of enzymes enable the one-pot combination of multiple otherwise incompatible catalysts for asymmetric cascade reactions that involve iminium, enamine, and H-bonding catalysis. Control experiments replacing star polymer catalysts with the corresponding small molecule or linear polymer analogues lead to little or no cascade reaction. Our strategy also allows straightforward access to all possible stereoisomers of the cascade product individually by proper choice of catalyst chirality. To our knowledge, this work represents the most sophisticated study of soluble polymers for site isolation, enzyme-like catalysis that generates cascade products with multiple chiral centers.
Utilizing synchronized 50 ps pulses from two independently tunable CO2 lasers, a pump–probe experiment is performed on pentafluorobenzene. The molecule, which has two infrared active modes accessible to the CO2 laser wavelengths, allows an extensive investigation into the statistical nature of the intramolecular vibrational energy relaxation process. We find discrete state effects, indicated by oscillatory behavior in the time-resolved absorption spectrum, disappear when the molecule is heated into the quasicontinuum. Using the anharmonic redshifting and broadening of the normal mode absorption features in the infrared spectrum as a measure of local temperature, our results indicate rapid equilibration (<50 ps) of absorbed energy among modes, with the final distribution of energy consistent with thermal heating.
Experimental confirmation has been made on a driven relaxation oscillator circuit, first presented by Van der Pol, of the periodadding route to chaos. The nonlinear element in the circuit is a neon bulb, modeled by a three-segment piecewise-linear current-controlled resistor. A simple nonlinear circuit model has been used to reproduce in simulations the experimentally-observed period-adding phenomenon.
Read moreNon-interpenetrating two star polymer catalysts designed to mimic the site isolation characteristics of enzymes enabled a one-pot asymmetric cascade reaction. Thus, the one-pot nucleophilic addition of 2 to 1 and Michael addition of the resulting 3 to 4 were performed with a star polymer salt catalyst 6˙7 (20 mol%) [prepared from an acidic star polymer 6 and imidazolidinone (S,S)-7], a pyrrolidine star polymer (S)-8 (20 mol%), and a catechol mediator 9 (1 mol equiv) to give ( R,S )-5 in 89% yield with >99% ee and 96% de. The use of 10 or 11 in place of 6 or 8 under similar conditions did not give 5.
Read moreA statistical approach is taken toward the ray optics of optical media with complicated nonspherical and nonplanar surface shapes. As a general rule, the light in such a medium will tend to be randomized in direction and of 2n2(x) times greater intensity than the externally incident light, where n(x) is the local index of refraction. A specific method for doing optical calculations in statistical ray optics will be outlined. These optical enhancement effects can result in a new type of antireflection coating. In addition, these effects can improve the efficiency as well as reduce the cost of solar cells.
Read moreTwo different bifurcation patterns are experimentally observed in Chua's circuit. They show that antimonotonicity — inevitable reversals of period-doubling sequences, is a typical phenomenon in Chua's circuit.
Read moreSurface recombination is an important characteristic of an optoelectronic material. Although surface recombination is a limiting factor for very small devices it has not been studied intensively. We have investigated surface recombination velocity on the exposed surfaces of the AlGaN, InGaAs, and InGaAlP material systems by using absolute photoluminescence quantum efficiency measurements. Two of these three material systems have low enough surface recombination velocity to be usable in nanoscale photonic crystal light-emitting diodes.
Read moreA nonoxide surface passivation for crystalline silicon is described. It involves the fluorination of the silicon surface. Characterization by photoconductive lifetime measurements and C–V measurements on MIS structures indicate that the fluorinated silicon surface is extraordinarily electrically passive, ≲1010 traps per cm2. Our technique for producing such high quality surfaces is described as is a novel gate insulator structure employing organic thin films. Potential device advantages of this alternative to oxide technology are also discussed.
Read moreWe describe how quantum information may be transferred from photon polarization to electron spin in a semiconductor device. The transfer of quantum information relies on selection rules for optical transitions, such that two superposed photon polarizations excite two superposed spin states. Entanglement of the electron spin state with the spin state of the remaining hole is prevented by using a single, non-degenerate initial valence band. The degeneracy of the valence band is lifted by the combination of strain and a static magnetic field. We give a detailed description of a semiconductor structure that transfers photon polarization to electron spin coherently, and allows electron spins to be stored and to be made available for quantum information processing.
Read moreAntenna arrays on conventional ground planes present different deficiencies. For compact platforms, the propagation of RF surface currents results in lost power, radiation from the edges and other discontinuities. It also contributes to the strong coupling and causes blind angles and multipath interference. By building radio isolation into the ground plane of phased array antenna structures, it is possible to reduce these different disturbances. This isolation may be achieved by using corrugated surfaces. In this case, DC currents are conducted but not AC currents. Based on the previous work done on PBG structure, a new kind of surface called High Impedance Ground Plane can be used. This kind of ground plane presents the same characteristics are corrugated surfaces in all the directions. Moreover the thickness must no longer be one fourth of the wavelength and can be even much smaller. These ground planes have been applied antenna array in order to reduce the disturbances created on compact platforms. Phase measurements of two-dipole array clearly shows this reduction.
Read moreFor maximal performance solar cells should resemble semiconductor lasers, i.e., they should be constructed in the form of a double heterostructure. We have found rather good performance in SIPOS-crystalline silicon-SIPOS double heterostructure solar cells, where SIPOS≡SiOx. The processing of these solar cells gives insights into the truly outstanding performance of the n+-SIPOS: p-Si heterojunction which has a forward saturation current coefficient J0=10−14 A/cm2, or equivalently an ‘‘emitter Gummel number’’ Ge=3.3×1015 s/cm4. This suggests that crystalline silicon solar cells can be much more efficient than had been suspected.
Read moreThe Internet has created a boom in long-distance optical communications. Web surfers click away and download ever-larger files, oblivious to their distance from a Web host. As a result the demand for capacity in undersea optical-fibre communications is escalating. A simple way to increase the capacity is to send many separate optical wavelengths through the same fibre, a technique known as wavelength division multiplexing. However, there is a limit to the optical power that can be used to send information along a fibre, and this – rather than the bandwidth of the fibre, which is prodigious – limits the capacity of optical fibres to carry information.
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